I-1-(1-Adamantylcarbonyl) proline (ACA) umkhiqizi we-powder CAS No.: 35084-48-1 98% ubumsulwa min.okwengeza izithako
Amapharamitha womkhiqizo
| Igama lomkhiqizo | 1-(1-Adamntylcarbonyl) proline |
| Elinye igama | 1-(1-ADAMANTYLCARBONYL)PYRROLIDINE-2-CARBOXYLIC ACID; I-1-(ADAMANTANE-1-CARBONYL)-PYRROLIDINE-2-CARBOXYLIC ACID; 1-(1-Adamantylcarbonyl)proline;L-Proline, 1-(tricyclo[3.3.1.13,7]dec-1-ylcarbonyl)- |
| Inombolo ye-CAS. | 35084-48-1 |
| Ifomula yamangqamuzana | I-C16H23NO3 |
| Isisindo samangqamuzana | 277.36 |
| Ubumsulwa | 98.0% |
| Ukubukeka | Impushana emhlophe |
| Ukupakisha | 1kg/isikhwama 10kg/isigubhu 25kg/isigubhu |
| Isicelo | I-Nootropic |
Isingeniso somkhiqizo
I-1-(1-Adamantylcarbonyl) iproline iphuma e-phenylalanine, eyaziwa nangokuthi i-adamantylproline noma i-Ad-Pro.Isetshenziswa kakhulu njenge-catalyst noma i-chiral resolution reagent ku-organic synthesis.Ucwaningo luye lwabonisa ukuthi i-proline engu-1-(1-Adamantylcarbonyl) ingakwazi ukuvuselela ukusabela kwe-nucleophilic asymmetric, njengokusabela phakathi kwama-aldehydes nama-alkylene azides, ukusabela phakathi kwe-aldehydes ne-sulfuryl folate, ukusabela phakathi kwe-aldehydes ne-nitromethane, njll. Phakathi kwalokhu kusabela, le catalyst inomsebenzi wokwengeza onamandla kakhulu kuma-alkylene azides.I-1-(1-Adamntylcarbonyl) i-proline ingase futhi idale ukusabela kwe-asymmetric amination.I-1-(1-Adamntylcarbonyl) i-proline ingasetshenziswa futhi njenge-chiral catalyst ukuze yenze i-asymmetric alcoholylation .Isibonelo, ingasabela otshwaleni nge-aldehydes noma ama-ketone ukuze inikeze i-aldol ehambisanayo noma imikhiqizo ye-hydroxyketone.I-1-(1-Adamntylcarbonyl) iproline, njengenhlanganisela ye-chiral organic, inomsebenzi omuhle kakhulu we-catalytic.Ngenxa yezakhiwo zayo ezihlukile ze-chiral, isetshenziswa kabanzi ku-chiral organic synthesis, okuhlanganisa ukusabela kwe-asymmetric nucleophilic add, ukusabela kwe-amination, ukusabela kokuphuza utshwala, njll.
Isici
(1) 1-(1-Adamntylcarbonyl) iproline iyimpushana emhlophe noma emhlophe futhi encibilika kahle.Inokuncibilika okuphansi emanzini, kodwa ngokuvamile inokuncibilika okuhle kuzincibilikisi zemvelo.Kuyinhlanganisela ezinzile engagcinwa isikhathi eside ekamelweni lokushisa.
(2) I-1-(1-Adamntylcarbonyl) i-proline i-molecule ye-chiral enama-enantiomers amabili.Imvelo yayo ye-chiral iyenza isetshenziswe kabanzi ku-chiral synthesis.Ngokuvamile, kufanele kusetshenziswe isomeri ye-chiral eyodwa kuphela ngenxa yokungeniswa kwayo okuhle kwe-chiral.
(3) I-1-(1-Adamntylcarbonyl) i-proline iyi-chiral organocatalyst esebenzayo ekwazi ukugqugquzela ukusabela okuhlukahlukene kwemvelo ngaphandle kwesidingo sezinsimbi.Ingase futhi ihlanganyele nama-molecule angaphansi ngokwakha amabhondi e-hydrogen noma ukubhanqa kwe-ion ukuze kuthuthukiswe ukusebenza kahle kokusabela nokukhetha.
(4) I-1-(1-Adamntylcarbonyl) i-proline isetshenziswa kakhulu ekuhlanganiseni kwe-chiral organic kanye nokusabela kwe-catalytic.Ingasetshenziswa njenge-chiral resolution reagent, i-chiral catalyst, i-chiral inducer, njll.
Izinhlelo zokusebenza
I-1-(I-Adamanane-1-carbonyl)-pyrrolidine-2-carboxylic acid iwuketshezi oluqukethe i-nitrogen, impushana emhlophe noma emhlophe, esetshenziswa njengendawo ephakathi noma emithini yokwelapha esetshenziselwa ukuqinisa ubuchopho, ukukhuthaza ubuhlakani, ukuvuselela, nokukhuthaza. ukuthuthukiswa kwezinzwa zobuchopho ezilimele.
